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Reactive Labels: Better Not Turn Red

Labels can do much more than impart printed information - they can now change color to let the consumer know about the freshness of their fish or meal, for instance. Kishore Sarkar from the Swiss label specialists, the Gallus Group, explains the functions of reactive labels, how they work and the opportunities they offer packaging specialists.

Mr. Sarkar, are reactive labels really useful or are they more of a gimmick?
Kishore Sarkar:
Labels with a so-called Time Temperature Indicator (TTI) are particularly valuable, above all in the food industry. They show deviations from the ideal cooling temperature by changing color when the temperature changes. That allows the consumer to see if the cold chain has been interrupted and how long the product will remain edible. This is especially useful with easily perishable goods like fresh fish, meat and prepared meals.

How does it work?
Sarkar:
If fish, for example, needs a cooling temperature of 41 degrees Fahrenheit (5 degrees centigrade), but the actual temperature is 33.8 to 41 degrees Fahrenheit (1-5 degrees centigrade) higher, an originally yellow label turns orange or red, or a dark blue one becomes light blue. This color change is irreversible: even if the food reaches the "correct" temperature again, the label retains the new color.

So cheating isn't possible…
Sarkar:
No, and that's a good thing. It isn't only a service for the end consumer, but much more a matter of consumer protection and avoidance of possible liability claims. The labels allow retail companies and logistics companies to be monitored. In some countries, such as the United States, for example, retail and logistics companies are legally required to make cooled foods retraceable through the entire supply chain.
Labels with a so-called Time Temperature Indicator (TTI) are particularly valuable, above all in the food industry. They show deviations from the ideal cooling temperature by changing color when the temperature changes
Labels with a so-called Time Temperature Indicator (TTI) are particularly valuable, above all in the food industry. They show deviations from the ideal cooling temperature by changing color when the temperature changes
Details Details
How does the color change work?
Sarkar:
The temperature range in which the printed color changes can be individually set based on the combination of printing inks. For this purpose, color pigments are calibrated so that their chemical structure changes at specific temperatures and thus reflects the light with a different color, either darker or lighter. There are currently colors for two temperature ranges: one for 32 to 39.2 degrees Fahrenheit (0-4 degrees centigrade) for meat, dairy and convenience products which last for up to 14 days. The other is for 41 degrees Fahrenheit (5 degrees centigrade) for fish and meat products which can be stored for five days.

Which printing processes are used here?
Sarkar:
The labels are usually produced using water-based flexographic printing or UV flexoprinting. Conventional offset printing is less suitable because the reactive labels require more ink application. That's because the color particles are enveloped by a protective microcapsule and are therefore larger than "normal" color particles. I'm sure that in a few years from now with the help of nanotechnology, we will be able to print these kinds of inks using offset.

Are there any special demands placed on printers in terms of room temperature during production and storage?
Sarkar:
No. The color, or more specifically the protective microcapsule layer is only activated during packaging - with the help of a LED-UV light.
What do you estimate to be the market potential?
Sarkar:
It is definitely growing because the retail trade is pushing the use of reactive labels. In England, Switzerland and the United States, consumers value this type of packaging, which is widespread. In Germany and Australia, the labels are already being used for several products. Demand will continue to grow particularly in Europe, because sales for convenience food are growing disproportionately here. Reactive labels, however, don't yet work on frozen products. An appropriate printing ink still has to be developed for this temperature range. In the future, the pharmaceutical and healthcare industry will increasingly look to reactive labels, for example for transporting blood bottles or temperature-sensitive medications.

Where else can you use reactive labels?
Sarkar:
People can use reactive labels on packaging where the goods are stored and sold in a defined atmosphere. Pigments like nano silver particles are used here. These react to gases which are emitted during the spoilage process. Take fresh fish for example. When it starts to spoil, hydrogen sulfide is generated. The nano silver particles react with the hydrogen sulfide to form silver sulfide, thus changing the color.

And in marketing?
Sarkar:
Labels printed with thermochromatic inks are very well-suited here. They show if a drink, for example wine or beer, is at the right serving temperature. These labels are primarily widespread in the United States on beer bottles. They are also used on bottled drinks in discos or bars. At a certain cooling temperature, the product logo glows noticeably. Thermochromatic colors are reversible. That means they can change their color time and again, for example from blue to red and back to blue again. Their applications are diverse, which is why printers are urged to inform and advise their customers.

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